(1,1'-Biphenyl)-4-carbonitrile, 4'-(hexyloxy)- → 4-(Hexyloxy)-4'-biphenylcarboxylic acid

関与物質

反応手順

In the synthesis of 4'-octyloxybiphenyl-4-carboxylic acid of Example 12, the same hydrolysis as in Example 12 was repeated except hat 4'-hexyloxy-4-cyanobiphenyl was used instead of 4'-octyloxy-4-cyanobiphenyl to obtain 4'-hexyloxybiphenyl-4-carboxylic acid. This 4'-hexyloxybiphenyl-carboxylic acid was condensed with (+)-4-(2-methylnonanoyl) phenol in the same manner as in the synthesis of 4-(2-metylnonanoyl) phenyl, 4'-octyloxybiphenyl-4-carboxylic acid ester of Example 13 to synthesize 4-(2-methylnonanoyl) phenyl, 4'-hexyloxybiphenyl-4-carboxylic acid ester having the aforementioned physical and chemical properties.

情報源と証拠