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(1,1'-Biphenyl)-4-carbonitrile, 4'-(nonyloxy)- → 4'-(Nonyloxy)[1,1'-biphenyl]-4-carboxylic acid
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | (1,1'-Biphenyl)-4-carbonitrile, 4'-(nonyloxy)- | HCID 100887 | — |
| 反応物 | 4'-(Octyloxy)-[1,1'-biphenyl]-4-carboxylic acid | HCID 2802556 | — |
| 生成物 | 4'-(Nonyloxy)[1,1'-biphenyl]-4-carboxylic acid | HCID 3620263 | — |
反応手順
In the synthesis of 4'-octyloxybiphenyl-4-caboxylic acid of Example 12, the same hydrolysis as in Example 12 was repeated except that 4'-nonyloxy-4-cyanobiphenyl was used instead of 4'-octyloxy-4-cyanobiphenyl to obtain 4'-nonyloxybiphenyl-4-carboxylic acid. This 4'-nonyloxybiphenyl-4-carboxylic acid was condensed with 4-(2-methylnonanoyl) phenol in the same manner as in the synthesis of 4-(2-methylnonanoyl) phenyl, 4'-octyloxybiphenyl-4-carboxylic acid ester of Example 13 to synthesize 4-(2-methylnonanoyl)phenyl, 4'-nonyloxybiphenyl-4-carboxylic acid ester having the aforementioned physical and chemical properties.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05137653 |
| 出典データセット | uspto-grants-1992_08 |
| ORD ID | ord-f7f9dc8d344f4e3797a454eaafb375b7 |
| 出典メモ | uspto-grants-1992_08 |