関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Acetonitrile | HCID 6342 | — |
| 反応物 | 1-Iodododecane | HCID 20282 | — |
| 反応物 | Trilauryl phosphite | HCID 76495 | — |
| 反応物 | N-Octadecyloctadecan-1-imine N-oxide | HCID 71340222 | — |
| 溶媒 | Toluene | HCID 1140 | — |
| 生成物 | Didodecyl P-[1-(N-Octadecyl-N-dodecyloxyamino)octadecyl]phosphonate | HCID 19883776 | 29% |
反応手順
Following the procedure of Example 7, the title compound is prepared from 2.5 g (4.6 mmol) of N-(1-octadecylidene)-octadecylamine N-oxide, 2.9 g (5.0 mmol) of tri-n-dodecylphosphite, 3.0 g (10 mmol) of n-dodecyl iodide, 20 ml of acetonitrile and 40 ml of toluene by heating at 70° C. for 24 hours. The residue is purified by flash chromatography (10:1 hexane:ethyl acetate eluent) to give 1.5 g (29% yield) of the title compound as a white, low melting wax.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 特許番号 | US05137951 |
|---|
| 出典データセット | uspto-grants-1992_08 |
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| ORD ID | ord-aac2045cc0d74fb3af58ec26691fc122 |
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| 出典メモ | uspto-grants-1992_08 |
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