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HRID 847470作成日:2026年10月27日

6-bromo-2,3,6-trideoxy-D-erythro-hexono-1,4-lactone → 6-bromo-2,3,6-trideoxy-L-erythro-hexono-1,4-lactone

https://huagongshe.com/reaction/847470

反応式

関与物質

役割名称HCID仕込み量
反応物6-bromo-2,3,6-trideoxy-D-erythro-hexono-1,4-lactoneHCID 11031067—
溶媒Chloroform-DHCID 71583—
生成物6-bromo-2,3,6-trideoxy-L-erythro-hexono-1,4-lactoneHCID 11805933—

反応手順

An 1H-NMR test carried out in the presence of a chiral shift-reagent [10 mg of compound No. 8 in deuterochloroform (0.6 ml) in the presence of Europhium (hfc)3 ] confirmed the absence of the 6-bromo-2,3,6-trideoxy-D-erythro-hexono-1,4-lactone enantiomer).

情報源と証拠

DOI10.6084/m9.figshare.5104873.v1
特許番号US05142066
出典データセットuspto-grants-1992_08
ORD IDord-f32ef307a9a34e8a97097a66d391f092
出典メモuspto-grants-1992_08