3-(Phenylthio)thiophene → HCID 88771909、化合物

HRID 848067ノート

反応式

HRID 848067 の反応式
[C:1]1([S:7][C:8]2[CH:12]=[CH:11][S:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:13]1([CH3:26])[CH:18]=[C:17]([CH3:19])[CH:16]=[C:15]([CH3:20])[C:14]=1[S:21]([O:24][NH2:25])(=[O:23])=[O:22]>ClCCl>[C:13]1([CH3:26])[CH:18]=[C:17]([CH3:19])[CH:16]=[C:15]([CH3:20])[C:14]=1[S:21]([OH:24])(=[O:23])=[O:22].[C:1]1([S:7]([C:8]2[CH:12]=[CH:11][S:10][CH:9]=2)=[NH:25])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

参加物

4

反応物 2

HCID 27789023-(Phenylthio)thiopheneHCID 11830845O-(2,4,6-Trimethylbenzenesulfonyl)hydroxylamine

生成物 1

HCID 88771909HCID 88771909、化合物収率 65%

試薬・触媒・溶媒 1

HCID 6344Dichloromethane溶媒

実験手順

In a manner analogous to that described in Example 1, Stage 1, from phenyl-(3-thienyl)-sulphide and O-mesitylsulphonyl-hydroxylamine in dichloromethane, there is obtained phenyl-(3-thienyl)-sulphimide mesitylene-sulphonate in a yield of 65% in theory; after recrystallisation from isopropanol, the compound melts at 116° C.

出典と根拠

ORDレコード
ord-c67bc925bfc2499bbb4d3ebde7b8540a
出典データセット
uspto-grants-1981_10
特許番号
US04294838

反応ノート

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