Diethyl Oxalate → HCID 178516908、化合物
反応式
[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([NH:8][C:9]2[C:10]([NH2:15])=[CH:11][CH:12]=[CH:13][CH:14]=2)=[CH:4][CH:3]=1.[C:16](OCC)(=[O:22])[C:17](OCC)=[O:18]>C(O)C>[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([N:8]2[C:9]3[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=3)[N:15]=[C:16]([OH:22])[C:17]2=[O:18])=[CH:4][CH:3]=1参加物
4
実験手順
N-(4-Chlorophenyl)benzene-1,2-diamine (11.2 g) was added to diethyl oxalate (50 ml) and the mixture heated under reflux for 2 hours. The mixture was cooled and ethanol (40 ml) was added. The precipitated solid was filtered off and recrystallised from ethanol giving the title compound (11.2 g) mp>300° C.
後処理
- temperaturethe mixture heated
- temperatureunder reflux for 2 hours
- temperatureThe mixture was cooled
- filtrationThe precipitated solid was filtered off
- customrecrystallised from ethanol giving the title compound (11.2 g) mp>300° C.
出典と根拠
- ORDレコード
- ord-5f67bd962ece4c348acec0776cac1378
- 出典データセット
- uspto-grants-1981_10
- 特許番号
- US04296114
反応ノート
読み込み中…