Naringin → Naringenin

HRID 848716

反応式

HRID 848716 の反応式
C[C@@H]1O[C@@H](O[C@H]2[C@H]([O:15][C:16]3[CH:17]=[C:18]([OH:34])[C:19]4[C:25](=[O:26])[CH2:24][C@@H:23]([C:27]5[CH:28]=[CH:29][C:30]([OH:33])=[CH:31][CH:32]=5)[O:22][C:20]=4[CH:21]=3)O[C@H](CO)[C@@H](O)[C@@H]2O)[C@H](O)[C@H](O)[C@H]1O>Cl>[CH:32]1[C:27]([C@H:23]2[O:22][C:20]3[CH:21]=[C:16]([OH:15])[CH:17]=[C:18]([OH:34])[C:19]=3[C:25](=[O:26])[CH2:24]2)=[CH:28][CH:29]=[C:30]([OH:33])[CH:31]=1

参加物

3

反応物 1

HCID 442428Naringin2 回

生成物 1

HCID 439246Naringenin

試薬・触媒・溶媒 1

HCID 313Hydrochloric Acid溶媒

実験手順

616.5 grams naringin were added to a round bottomed flask, followed by the addition of about one liter of 0.5 N hydrochloric acid. Upon stirring and refluxing, the naringin dissolves to form a yellow to red-brown solution. While a brown gummy or oily material initially forms, it eventually disappears. As the reaction proceeds, a yellow solid precipitates. The reaction time is approximately 2 to 4 hours. The solution is cooled, and the yellow solid filtered and washed with copious amounts of water until the washings are no longer acidic. The amount of naringenin produced is about 160 grams.

後処理

  1. temperaturerefluxing
  2. customto form a yellow to red-brown solution
  3. customAs the reaction proceeds
  4. customa yellow solid precipitates
  5. temperatureThe solution is cooled
  6. filtrationthe yellow solid filtered
  7. washwashed with copious amounts of water until the washings

出典と根拠

ORDレコード
ord-29a10da464654caca79df4dcc547a114
出典データセット
uspto-grants-1981_10
特許番号
US04297348

関連ノート

読み込み中…