化工社化工社 化学情報印刷レポート · 研究参考用
1-Dodecene → n-Dodecyldichlorosilane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1-Dodecene | HCID 8183 | — |
| 反応物 | Dichlorosilane | HCID 61330 | — |
| 触媒 | Nickel Dichloride | HCID 24385 | — |
| 生成物 | n-Dodecyldichlorosilane | HCID 123720552 | — |
反応手順
Dichlorosilane in an amount of 75.8 g (0.75 mol), 228.5 g of 1-dodecene (1.36 mol) and 0.05 mol % of a catalyst NiCl2 --(PPh3)2 (relative to dichlorosilane) were charged in a 500 ml pressure-proof stainless steel reactor and sealed. A reaction was carried out at 100° C. for 30 hours and the reacted liquid was distilled to obtain n-dodecyldichlorosilane (n--C12H25SiHCl2).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04297499 |
| 出典データセット | uspto-grants-1981_10 |
| ORD ID | ord-619ad426c84a4feb889b047bc5e498c7 |
| 出典メモ | uspto-grants-1981_10 |