化工社化工社 化学情報印刷レポート · 研究参考用
Gadolinium → Aluminum isopropoxide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Gadolinium | HCID 23982 | — |
| 反応物 | Yttrium | HCID 23993 | — |
| 反応物 | Acetylacetone | HCID 31261 | — |
| 反応物 | Aluminum | HCID 5359268 | — |
| 反応物 | Gallium | HCID 5360835 | — |
| 溶媒 | Ethylene Glycol | HCID 174 | — |
| 溶媒 | 2-Methoxyethanol | HCID 8019 | — |
| 溶媒 | 1-Methoxyethanol | HCID 3015637 | — |
| 生成物 | Aluminum isopropoxide | HCID 11143 | — |
| 生成物 | Yttrium(iii) isopropoxide | HCID 11550724 | — |
| 生成物 | Gadolinium (III) isopropoxide | HCID 15047187 | — |
| 生成物 | Gallium (III) isopropoxide | HCID 22253272 | — |
反応手順
Sol-gel libraries were deposited on silicon wafer substrates. Stock solutions of yttrium isopropoxide, aluminum isopropoxide, gadolinium isopropoxide and gallium isopropoxide were prepared in 2-methoxyethanol (0.25 M) refluxing under Argon for 8 hours. To each of the four stock solutions of yttrium, gadolinium, aluminum and gallium in methoxyethanol (0.25 M), 1 equivalent of 2,4-pentandione was added with stirring, followed by the addition of anhydrous ethylene glycol (15% v/v). The yttrium and gadolinium solutions contained Ce(NO)3.6H2O at 1.0 mol % as the dopant source.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06013199 |
| 出典データセット | uspto-grants-2000_01 |
| ORD ID | ord-724c5c93a2274e7bba9178077f8adbb3 |
| 出典メモ | uspto-grants-2000_01 |