関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Water | HCID 962 | — |
| 反応物 | ((Phenylthioxomethyl)thio)acetic acid | HCID 70336 | — |
| 反応物 | tert-Butylhydrazine monohydrochloride | HCID 81889 | — |
| 溶媒 | Pyridine | HCID 1049 | — |
| 生成物 | N'-t-butyl-N-(thiobenzoyl)hydrazine | HCID 19367775 | — |
反応手順
S-(thiobenzoyl)thioglycolic acid (3.0 g) was dissolved in 20 ml pyridine, treated with t-butyl hydrazine hydrochloride (excess, ca. 4 g) and then was heated at ca. 120° C. for 14 hours. Water (120 ml) was added and the mixture was extracted with ether. The organic extracts were dried over anhydrous magnesium sulfate, filtered and evaporated to give crude N'-t-butyl-N-(thiobenzoyl)hydrazine as a viscous yellow oil.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US06013836 |
|---|
| 出典データセット | uspto-grants-2000_01 |
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| ORD ID | ord-94d56aaa95654b0b938589fcabec5f99 |
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| 出典メモ | uspto-grants-2000_01 |
|---|
