Methyl((4-phenylphenyl)methyl)amine → HCID 86755085、化合物
反応式
CNCC1C=CC(C2C=CC=CC=2)=CC=1.[CH3:16][C:17]([CH3:39])([CH3:38])[C:18]#[C:19]/[CH:20]=[CH:21]/[CH2:22][N:23]([CH2:25][C:26]1[CH:31]=[CH:30][C:29]([C:32]2[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=2)=[CH:28][CH:27]=1)[CH3:24]>>[CH3:16][C:17]([CH3:39])([CH3:38])[C:18]#[C:19]/[CH:20]=[CH:21]\[CH2:22][N:23]([CH2:25][C:26]1[CH:27]=[CH:28][C:29]([C:32]2[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=2)=[CH:30][CH:31]=1)[CH3:24]参加物
3
実験手順
N-methyl-4-phenylbenzylamine (0.75 g) was processed in a similar manner as in Synthesis Example 5, whereby trans-N-(6,6-dimethyl-2-hepten-4-yn-1-yl)-N-methyl-4-phenylbenzylamine (Compound 9) and cis-N-(6,6-dimethyl-2-hepten-4-yn-1-yl)-N-methyl-4-phenylbenzylamine (Compound 10) were obtained in amounts of 0.52 g (yield: 45%) and 0.12 g (yield: 10.4%), respectively. The followings are their NMR spectrum data:
出典と根拠
- ORDレコード
- ord-5847bdecf415429180cefe607d7c0467
- 出典データセット
- uspto-grants-2000_01
- 特許番号
- US06015925