Gluconic Acid → 2-keto-D-Gluconic acid

HRID 850689

反応式

HRID 850689 の反応式
O=C[C@@H]([C@H]([C@@H]([C@@H](CO)O)O)O)O.[O:13]=[C:14]([OH:25])[C@@H:15]([C@H:17]([C@@H:19]([C@@H:21]([CH2:23][OH:24])[OH:22])[OH:20])[OH:18])[OH:16]>>[CH2:23]([OH:24])[C@@H:21]([OH:22])[C@@H:19]([OH:20])[C@H:17]([OH:18])[C:15]([C:14]([OH:25])=[O:13])=[O:16]

参加物

3

反応物 2

HCID 10690Gluconic AcidHCID 107526(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal

生成物 1

HCID 30354562-keto-D-Gluconic acid

実験手順

It is shown in Examples 7 to 9 that starting from D-glucose it is preferable to start at higher pH to prepare the intermediate, D-gluconic acid, and after equimolar consumption of alkali (sodium hydroxide, potassium hydroxide, sodium carbonate, etc.) a pH drop to 5.0 or below 5.0 is allowed, to obtain high yields of 2-keto-D-gluconic acid.

後処理

  1. customafter equimolar consumption of alkali (sodium hydroxide, potassium hydroxide, sodium carbonate, etc.) a pH drop to 5.0
  2. customto obtain high

出典と根拠

ORDレコード
ord-76fd5a369aab4c5d899c2d019246c8a1
出典データセット
uspto-grants-2000_01
特許番号
US06018034

関連ノート

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