Methylamine → HCID 178484896、化合物

HRID 851751ノート

反応式

HRID 851751 の反応式
[C:1]([NH:3][CH:4]=[N:5][C:6]1[CH:11]=[CH:10][C:9]([C:12]2[N:13]=[CH:14][NH:15][CH:16]=2)=[CH:8][CH:7]=1)#N.CN>O>[CH3:1][NH:3][CH:4]=[N:5][C:6]1[CH:11]=[CH:10][C:9]([C:12]2[N:13]=[CH:14][NH:15][CH:16]=2)=[CH:8][CH:7]=1

参加物

4

反応物 2

HCID 6329MethylamineHCID 178512241HCID 178512241、化合物

生成物 1

HCID 178484896HCID 178484896、化合物収率 70.9%

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

Twenty grams of N-cyano-N'-[4-(imidazol-4-yl)-phenyl]-formamidine was added in one portion to 35% methylamine in water (70 ml). A few minutes after the addition, the solid N-methyl-N'-[4-(imidazol-4-yl)-phenyl]-formamidine separated out of the solution. This solid was collected by filtration, washed with water, and dried to yield 13.45 gm of the desired product, which was recrystallized from acetone.

後処理

  1. additionA few minutes after the addition
  2. customthe solid N-methyl-N'-[4-(imidazol-4-yl)-phenyl]-formamidine separated out of the solution
  3. filtrationThis solid was collected by filtration
  4. washwashed with water
  5. customdried

出典と根拠

ORDレコード
ord-c10122252efb46e1b065829d38281324
出典データセット
uspto-grants-1983_05
特許番号
US04386099

反応ノート

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