1-Chloro-4-iodobenzene → {4-[3-(4-Chloro-phenyl)-prop-2-ynylsulfanyl]-2-methyl-phenoxy}-acetic acid tert-butyl ester

HRID 852369ノート

反応式

HRID 852369 の反応式
[C:1]([O:5][C:6](=[O:20])[CH2:7][O:8][C:9]1[CH:14]=[CH:13][C:12]([S:15][CH2:16][C:17]#[CH:18])=[CH:11][C:10]=1[CH3:19])([CH3:4])([CH3:3])[CH3:2].[Cl:21][C:22]1[CH:27]=[CH:26][C:25](I)=[CH:24][CH:23]=1>>[C:1]([O:5][C:6](=[O:20])[CH2:7][O:8][C:9]1[CH:14]=[CH:13][C:12]([S:15][CH2:16][C:17]#[C:18][C:25]2[CH:26]=[CH:27][C:22]([Cl:21])=[CH:23][CH:24]=2)=[CH:11][C:10]=1[CH3:19])([CH3:4])([CH3:3])[CH3:2]

参加物

3

反応物 2

HCID 125101-Chloro-4-iodobenzeneHCID 86602538(2-Methyl-4-prop-2-ynylsulfanyl-phenoxy)-acetic acid tert-butyl ester

生成物 1

HCID 69461193{4-[3-(4-Chloro-phenyl)-prop-2-ynylsulfanyl]-2-methyl-phenoxy}-acetic acid tert-butyl ester

実験手順

In analogy to the procedure described in example 5B], (2-methyl-4-prop-2-ynylsulfanyl-phenoxy)-acetic acid tert-butyl ester (example 5A]) and 1-chloro-4-iodo-benzene gave the title compound as a light yellow oil.

出典と根拠

ORDレコード
ord-f657bee1155f445e81a39d82e5cf14f3
出典データセット
uspto-grants-2007_08
特許番号
US07253192B2

反応ノート

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