3-Tetradecylthioacetylamino-2-tetradecylthioacetylthio-1-triphenylmethyloxypropane → 3-Tetradecylthioacetylamino-2-tetradecylthioacetylthiopropan-1-ol
反応式
[CH2:1]([CH2:15][C:16]([NH:18][CH2:19][CH2:20][CH:21]([S:42][C:43](=[S:59])[CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH2:53][CH2:54][CH2:55][CH2:56][CH2:57][CH3:58])[O:22]C(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1)=[S:17])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14]>CCOCC.Cl>[CH2:1]([CH2:15][C:16]([NH:18][CH2:19][CH2:20][CH:21]([S:42][C:43](=[S:59])[CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH2:53][CH2:54][CH2:55][CH2:56][CH2:57][CH3:58])[OH:22])=[S:17])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14]参加物
4
実験手順
3-tetradecylthioacetylamino-2-tetradecylthioacetylthio-1-triphenylmethyloxy-propane (example 20d) (187 mg, 0.21 mmol) was dissolved in ether saturated with gaseous hydrochloric acid (12 ml). The reaction medium was stirred at room temperature for 20 hours. The precipitate which formed was filtered and washed with diethyl ether to give the desired compound in the form of a white powder.