Methanol → HCID 178498891、化合物
反応式
C[C:2]#[C:3][C:4]([O-:6])=[O:5].C[Si]([N:11]=[N+:12]=[N-:13])(C)C.[CH3:14]O>>[NH:11]1[CH:2]=[C:3]([C:4]([O:6][CH3:14])=[O:5])[N:13]=[N:12]1参加物
4
反応条件
- 温度
- 105 °C
実験手順
Methylpropiolate (20 g) and trimethylsilyl azide (68.6 g) were added to a pressure-resistant tube, and the mixture was stirred for 72 hours at 105° C. After allowing the mixture to be cooled to room temperature, methanol was added to the mixture, and the solvent was removed under reduced pressure, and the obtained residue was washed with diethylether/methanol to give methyl 1,2,3-triazole-4-carboxylate (22.7 g).
後処理
- temperatureto be cooled to room temperature
- customthe solvent was removed under reduced pressure
- washthe obtained residue was washed with diethylether/methanol
出典と根拠
- ORDレコード
- ord-bb5e55f2827b490c9a28801e2218d0b7
- 出典データセット
- uspto-grants-2007_08
- 特許番号
- US07262185B2
反応ノート
読み込み中…