Glyoxal → Glyoxal guanine

HRID 857827

反応式

HRID 857827 の反応式
[NH:1]1[C:10](=[O:11])[C:9]2[NH:8][CH:7]=[N:6][C:5]=2[N:4]=[C:2]1[NH2:3].[CH:12]([CH:14]=[O:15])=[O:13]>O>[CH:12]([CH:14]=[O:15])=[O:13].[NH:1]1[C:10](=[O:11])[C:9]2[NH:8][CH:7]=[N:6][C:5]=2[N:4]=[C:2]1[NH2:3]

参加物

4

反応物 2

HCID 7860GlyoxalHCID 135398634Guanine

生成物 1

HCID 136394281Glyoxal guanine

試薬・触媒・溶媒 1

HCID 962Water溶媒

反応条件

温度
70 °C

実験手順

22.65 g of guanine (manufactured by Tokyo Kasei Kogyo Co.) and 21.75 g of a 40% glyoxal aqueous solution (manufactured by Tokyo Kasei Kogyo Co.) were added to 950 mL of purified water, and the mixture was stirred with heating at 70° C. for 18 hours. The mixture was then cooled to 4° C. and filtered. The white solid obtained by the filtration was dried, thereby resulting in 30.7 g of glyoxal-guanine. The measurement result of nuclear magnetic resonance (NMR) spectrum is as follows:

後処理

  1. temperatureThe mixture was then cooled to 4° C.
  2. filtrationfiltered
  3. customThe white solid obtained by the filtration
  4. customwas dried
  5. customresulting in 30.7 g of glyoxal-guanine
  6. customThe measurement result of nuclear magnetic resonance (NMR) spectrum

出典と根拠

ORDレコード
ord-239085e5c8894dd89ad6fbf370bbf65d
出典データセット
uspto-grants-2006_12
特許番号
US07148042B2

関連ノート

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