関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Formic Acid | HCID 284 | — |
| 反応物 | 1-Butene | HCID 7844 | — |
| 反応物 | Levulinic Acid | HCID 11579 | — |
| 反応物 | Trifluoromethanesulfonic acid | HCID 62406 | — |
| 生成物 | Butyl levulinate | HCID 16331 | — |
反応手順
A 5 cc autoclave is charged with 2 cc of an aqueous solution containing 2 mmoles of levulinic acid and 0.5 mmoles of formic acid. 2 wt. % triflic acid is added as a catalyst. The reactor is pressurized to 0.69 MPa with 1-butene and heated to 100° C. for 0.5 hours while maintaining a constant pressure of 1-butene. After cooling, the organic phase is separated. A mixture of butyl formate and butyl levulinate is formed as product.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US07153996B2 |
|---|
| 出典データセット | uspto-grants-2006_12 |
|---|
| ORD ID | ord-d6aa30770f634ac0bc7c11423de4a1ab |
|---|
| 出典メモ | uspto-grants-2006_12 |
|---|
