HCID 22097108、化合物 → HCID 22097099、化合物
反応式
[Cl:1][C:2]1[CH:3]=[CH:4][C:5]([N+:13]([O-])=O)=[C:6]([NH:8][CH2:9][C:10]([OH:12])=[O:11])[CH:7]=1>C(O)C.[Ni]>[NH2:13][C:5]1[CH:4]=[CH:3][C:2]([Cl:1])=[CH:7][C:6]=1[NH:8][CH2:9][C:10]([OH:12])=[O:11]参加物
4
実験手順
19.5 g (84.6 mmol) of N-(5-chloro-2-nitrophenyl)glycine were dissolved in 250 ml of ethanol and, after addition of 5 g of Raney nickel, hydrogenated under 1 bar at 45°-50° C. The mixture was then filtered, and the filtrate was evaporated under reduced pressure to yield 15.6 g (93%) of the product.
後処理
- customat 45°-50° C
- filtrationThe mixture was then filtered
- customthe filtrate was evaporated under reduced pressure
出典と根拠
- ORDレコード
- ord-1ac282306242471383ca59b6ec939516
- 出典データセット
- uspto-grants-1998_02
- 特許番号
- US05714489
反応ノート
読み込み中…