Stearyl acrylate → HCID 19704419、化合物

HRID 861666

反応式

HRID 861666 の反応式
[CH3:1][C:2]1([CH3:28])[CH2:7][CH:6]([NH:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][NH:15][CH:16]2[CH2:21][C:20]([CH3:23])([CH3:22])[NH:19][C:18]([CH3:25])([CH3:24])[CH2:17]2)[CH2:5][C:4]([CH3:27])([CH3:26])[NH:3]1.[CH:29](N)(N)[CH2:30][CH2:31][CH2:32][CH2:33][CH3:34].[C:37]([O:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH2:53][CH2:54][CH2:55][CH2:56][CH2:57][CH2:58][CH3:59])(=[O:40])[CH:38]=[CH2:39]>CO>[CH2:29]([O:41][C:37]([CH2:38][CH2:39][N:8]([CH:6]1[CH2:7][C:2]([CH3:28])([CH3:1])[NH:3][C:4]([CH3:27])([CH3:26])[CH2:5]1)[CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][N:15]([CH2:39][CH2:38][C:37]([O:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH2:53][CH2:54][CH2:55][CH2:56][CH2:57][CH2:58][CH3:59])=[O:40])[CH:16]1[CH2:17][C:18]([CH3:25])([CH3:24])[NH:19][C:20]([CH3:23])([CH3:22])[CH2:21]1)=[O:40])[CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH3:53]

参加物

5

反応物 3

HCID 62552Stearyl acrylateHCID 934191,6-Bis(2,2,6,6-tetramethyl-4-piperidylamino)hexaneHCID 134940Hexanediamine

生成物 1

HCID 19704419HCID 19704419、化合物

試薬・触媒・溶媒 1

HCID 887Methanol溶媒3 回

実験手順

To a 1-liter four-necked flask were added 20 g (50 mmoles) of N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)-1,6-hexanediamine and 200 g of methanol, and the hexanediamine was completely dissolved in the methanol. To the resulting solution was added dropwise a solution of 32.4 g (0.1 mole) of octadecyl acrylate in 100 g of methanol at room temperature, after which reaction was continued for 12 hours under reflux. The solvent was removed by evaporation, and FD-MS measurement was carried out. As a result, it was found that N-(2-octadecyloxycarbonylethyl)-N,N'-bis(2,2,6,6-tetrametyl-4-piperidyl)-1,6-hexanediamine was produced in a small amount, but Compound O was not confirmed.

後処理

  1. customafter which reaction
  2. temperatureunder reflux
  3. customThe solvent was removed by evaporation, and FD-MS measurement

出典と根拠

ORDレコード
ord-230bd3aa503b4e20b4716e03ae718dd0
出典データセット
uspto-grants-1998_02
特許番号
US05714612

関連ノート

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