1,3-Cyclopentadiene, 5-(1-methylethylidene)- → Lithium tert-butylcyclopentadienide

HRID 863390ノート

反応式

HRID 863390 の反応式
[CH3:1][C:2]([CH3:8])=[C:3]1[CH:7]=[CH:6][CH:5]=[CH:4]1.[CH3:9][Li:10]>C(OCC)C>[C:2]([C-:3]1[CH:7]=[CH:6][CH:5]=[CH:4]1)([CH3:9])([CH3:8])[CH3:1].[Li+:10]

参加物

4

反応物 2

HCID 1374671,3-Cyclopentadiene, 5-(1-methylethylidene)-HCID 178418348HCID 178418348、化合物

生成物 1

HCID 12713396Lithium tert-butylcyclopentadienide

試薬・触媒・溶媒 1

HCID 3283Diethyl Ether溶媒2 回

実験手順

To a solution of 4.18 g (39.4 mmol) 6,6-dimethylfulvene in 80 mL diethylether at 0° C. were added 22.9 mL of a 1.72M (39.4 mmol) methyl lithium solution in ether. The resulting slurry was stirred several days, then filtered, washed with pentane and dried under vacuum.

後処理

  1. filtrationfiltered
  2. washwashed with pentane
  3. customdried under vacuum

出典と根拠

ORDレコード
ord-019418057763452d91d933b124ed72ee
出典データセット
uspto-grants-1998_02
特許番号
US05721185

反応ノート

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