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tert-Butyl hydroperoxide → HCID 19050660、化合物
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | tert-Butyl hydroperoxide | HCID 6410 | — |
| 反応物 | HCID 19050670 | HCID 19050670 | — |
| 触媒 | Dicobalt Octacarbonyl (stabilized with 1-5% Hexane) | HCID 25049 | — |
| 溶媒 | Acetonitrile | HCID 6342 | — |
| 生成物 | HCID 19050660 | HCID 19050660 | — |
反応手順
A solution of 100 mg of N-methyl 3-phenyl-5-(4,6-dimethoxy-2-pyrimidinylmethyl)-4-isoxazolecarboxanilide, 20 mg of dicobalt octacarbonyl, and 1 ml of t-butylhydroperoxide, in 60 ml of acetonitrile is refluxed for 48 hours. An additional 1 ml of t-butylhydroperoxide is added after 12 hrs and 24 hrs. Thin layer chromatography after 48 hrs indicates the presence of starting material and the title compound.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05561101 |
| 出典データセット | uspto-grants-1996_10 |
| ORD ID | ord-776e651b363d4802847ce5c4cfead691 |
| 出典メモ | uspto-grants-1996_10 |