Benzyl Bromide → HCID 86749956、化合物

反応式

[CH2:1]([O:3][CH:4]([C:8]1[N:9]([CH3:13])[CH:10]=[CH:11][N:12]=1)[O:5][CH2:6][CH3:7])[CH3:2].[CH2:14]([Br:21])[C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1>>[Br-:21].[CH2:14]([N:12]1[CH:11]=[CH:10][N+:9]([CH3:13])=[C:8]1[CH:4]([O:3][CH2:1][CH3:2])[O:5][CH2:6][CH3:7])[C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1

参加物

反応物 2

HCID 7498Benzyl Bromide

HCID 5741401H-Imidazole, 2-(diethoxymethyl)-1-methyl-

生成物 1

HCID 86749956HCID 86749956、化合物収率 98.3%

実験手順

A reaction mixture of 8 g (43 mmol) of 2-(diethoxymethyl-1-methyl-imidazole and 7.44 g (43 mmol) of benzyl bromide was stirred at room temperature overnight. The mixture was triturated with ethyl acetate and decanted to afford 15.1 g (98.3%) of 3-benzyl-2-(diethoxymethyl)-1-methylimidazolium bromide (Formula VI: A=1-methylimidazole;Y=CH--(OC2H5)2 ;R1 =R6 =H;Z- =Br-).

後処理

customThe mixture was triturated with ethyl acetate
customdecanted

出典と根拠

ORDレコード: ord-0fa2a88d7ea14a96b418f6d0f02c6c0e
出典データセット: uspto-grants-1996_10
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US05569655

反応ノート

読み込み中…

参加物