tert-Butyl hydroperoxide → HCID 20318133、化合物

反応式

[C:1](N=NC(Cl)(C)C)(C)(C)[CH3:2].[K].C(OO)(C)(C)C.[C:18]([N:22]=[N:23][C:24]([O:27][O:28][C:29]([CH3:32])(C)C)([CH3:26])[CH3:25])([CH3:21])([CH3:20])[CH3:19].C(N=NC(O)(C)C)(C)(C)C>>[C:18]([N:22]=[N:23][C:24]([O:27][O:28][CH2:29][CH2:32][CH2:1][CH3:2])([CH3:25])[CH3:26])([CH3:19])([CH3:20])[CH3:21]

参加物

反応物 5

HCID 6410tert-Butyl hydroperoxide

HCID 945822-Propanol, 2-((1,1-dimethylethyl)azo)-

HCID 5462222Potassium

HCID 156443492-t-Butylazo-2-chloropropane

HCID 20393238HCID 20393238、化合物

生成物 1

HCID 20318133HCID 20318133、化合物

実験手順

Crude 2-t-butylazo-2-butylperoxypropane was prepared by reacting 2-t-butylazo-2-chloropropane with an aqueous solution of the potassium salt of t-butyl hydroperoxide according to the method described in MacLeay, Lange and Sheppard application Ser. No. 426,411 filed Dec. 19, 1973, (which is incorporated herein by reference). The resultant product contained approximately 75% 2-t-butylazo -2-t-butylperoxypropane and 25% 2-t-butylazo-2-hydroxy-propane (which has been marketed as "LUCEL 3").