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Dinitrofluorobenzene → 1-(2-Acetamidoethyl)-5-(2,4-dinitrophenylthio)tetrazole
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Dinitrofluorobenzene | HCID 6264 | — |
| 反応物 | Triethylamine | HCID 8471 | — |
| 反応物 | HCID 178474869 | HCID 178474869 | — |
| 溶媒 | Acetone | HCID 180 | — |
| 生成物 | 1-(2-Acetamidoethyl)-5-(2,4-dinitrophenylthio)tetrazole | HCID 20382814 | — |
反応手順
A solution of 9.3 g (0.050 mol) of 2.4-dinitrofluorobenzene in 50 ml of acetone was added to a solution of 9.35 g (0.050 mol) of 1-(2-acetamidoethyl)tetrazole-5-thiol and 6.85 ml (0.050 mol) of triethylamine in 100 ml of acetone and the reaction mixture was stirred for 1 hour. The solid material was collected by filtration and recrystallized from acetonitrile to give 1-(2-acetamidoethyl)-5-(2,4-dinitrophenylthio)tetrazole, mp 197°-198°.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04101656 |
| 出典データセット | uspto-grants-1978_07 |
| ORD ID | ord-a4e3ec16fcfe4162ad1cea7b33baf463 |
| 出典メモ | uspto-grants-1978_07 |