化工社化工社 化学情報印刷レポート · 研究参考用
Allyl chloride → 1-(3,3-Dimethylcyclohexyl)ethanone
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Allyl chloride | HCID 7850 | — |
| 反応物 | Triethylamine | HCID 8471 | — |
| 反応物 | Sodium Hydroxide | HCID 14798 | — |
| 反応物 | 1-(3,3-Dimethylcyclohexyl)ethanone | HCID 91388 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | 1-(3,3-Dimethylcyclohexyl)ethanone | HCID 91388 | — |
| 生成物 | 1-(3,3-Dimethylcyclohexyl)-pent-4-en-1-one | HCID 6453423 | — |
| 生成物 | 1-Acetyl-3,3-dimethyl-1-(2-pentenyl) cyclohexane | HCID 53724607 | — |
反応手順
A mixture of 1-acetyl-3,3-dimethylcyclohexane (156 grams, 1 mole), sodium hydroxide (60 grams, 1.5 moles), allyl chloride (114 grams, 1.5 moles) and triethylamine (10 grams) is stirred and heated at 80°-84° C. for 12 hours. The reaction mass is cooled to room temperature. Water is added with stirring, and the aqueous layer is discarded. The organic layer is distilled to afford 119 grams of 1-acetyl-3,3-dimethylcyclohexane, 31 grams of 1-acetyl-3,3-dimethyl-1-(2-pentenyl) cyclohexane, and 5 grams of 3,3-dimethyl-1-(4-pentenoyl) cyclohexane.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04102928 |
| 出典データセット | uspto-grants-1978_07 |
| ORD ID | ord-eea4779a8076450b860971bd9ec322b9 |
| 出典メモ | uspto-grants-1978_07 |