2-Fluoro-4-(trifluoromethyl)pyridine → 2-Azido-5-(trifluoromethyl)pyridine
反応式
[N:1]([C:4]1[CH:9]=[C:8](C(F)(F)F)[CH:7]=[CH:6][N:5]=1)=[N+:2]=[N-:3].FC1C=C([C:21]([F:24])([F:23])[F:22])C=CN=1>>[N:1]([C:4]1[CH:9]=[CH:8][C:7]([C:21]([F:24])([F:23])[F:22])=[CH:6][N:5]=1)=[N+:2]=[N-:3]参加物
3
実験手順
The following were prepared analogously and analyzed by nmr spectroscopy: 2-azido-4-(trifluoromethyl)pyridine, off white crystals (from 2-fluoro-4-(trifluoromethyl)pyridine; and 2-azido-4,6-bis(trifluoromethyl)pyridine, pale yellow oil crystallizing on standing (from 2-chloro-4,6-bis(trifluoromethyl)pyridine.
後処理
- customThe following were prepared analogously
- customand 2-azido-4,6-bis(trifluoromethyl)pyridine, pale yellow oil crystallizing
出典と根拠
- ORDレコード
- ord-6f04ff5df6b64738a0bedaf065594398
- 出典データセット
- uspto-grants-1988_10
- 特許番号
- US04775762
反応ノート
読み込み中…