Acetone → N-[(4,6-Dimethoxy-1,3,5-triazin-2-yl)aminocarbonyl]-3-pyridinesulfonamide

HRID 867840ノート

反応式

HRID 867840 の反応式
[CH3:1][O:2][C:3]1[N:8]=[C:7]([O:9][CH3:10])[N:6]=[C:5]([NH:11][C:12](=S)[NH:13][S:14]([C:17]2[CH:18]=[N:19][CH:20]=[CH:21][CH:22]=2)(=[O:16])=[O:15])[N:4]=1.CC(C)=[O:26]>>[CH3:1][O:2][C:3]1[N:8]=[C:7]([O:9][CH3:10])[N:6]=[C:5]([NH:11][C:12]([NH:13][S:14]([C:17]2[CH:18]=[N:19][CH:20]=[CH:21][CH:22]=2)(=[O:16])=[O:15])=[O:26])[N:4]=1

参加物

3

反応物 2

HCID 180AcetoneHCID 13533309N-[(4,6-dimethoxy-1,3,5-triazin-2-yl)aminothioxomethyl]-3-pyridinesulfonamide

生成物 1

HCID 13533305N-[(4,6-Dimethoxy-1,3,5-triazin-2-yl)aminocarbonyl]-3-pyridinesulfonamide

実験手順

A mixture containing 2.7 g of N-[(4,6-dimethoxy-1,3,5-triazin-2-yl)aminothioxomethyl]-3-pyridinesulfonamide, 2.98 g of mercuric oxide and 75 ml of acetone was stirred at ambient temperature for 60 hours and then filtered. Evaporation of the filtrate in vacuo yielded the desired product as a residual white solid of m.p. 182°-185° dec.

後処理

  1. filtrationfiltered
  2. customEvaporation of the filtrate in vacuo

出典と根拠

ORDレコード
ord-bcd4295b9dc948cb8c99a7f5b116659e
出典データセット
uspto-grants-1988_10
特許番号
US04776878

反応ノート

読み込み中…