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Allyl phenyl ether → HCID 14328878、化合物
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Allyl phenyl ether | HCID 74458 | — |
| 反応物 | 2-(1H-Imidazol-1-yl)-N-methyl-1-(2-naphthalenyl)ethanimine N-oxide | HCID 86742472 | — |
| 溶媒 | Toluene | HCID 1140 | — |
| 生成物 | HCID 14328878 | HCID 14328878 | — |
反応手順
A mixture of compound 2 (9.0 g, 0.034 mol) and phenyl allyl ether (6.98 ml, 0.051 mol) in 200 ml of toluene is refluxed for 48 hours, cooled and evaporated under vacuum. The semisolid that remained (7.30 g, 54%) is crystallized from ether and recrystallized from ethyl acetate to give tan crystals. Yield: 2.4 g (18%); m.p. 176°-178° C. (Found: C, 74.96; H, 6.41; N, 10.40. C25H25N3O2 requires: C, 75.16; H, 6.31; N, 10.52).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04777263 |
| 出典データセット | uspto-grants-1988_10 |
| ORD ID | ord-40739d68791d434b838e2b7febef88e8 |
| 出典メモ | uspto-grants-1988_10 |