Phenol → HCID 13828077、化合物
反応式
[S:1](=[O:5])(=O)([OH:3])[OH:2].[C:6]1([OH:12])[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1.[C:13](Cl)(=[O:22])[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH:19]([CH3:21])[CH3:20]>>[C:13]([O:12][C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][C:7]=1[S:1]([OH:3])(=[O:5])=[O:2])(=[O:22])[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH:19]([CH3:21])[CH3:20]参加物
4
反応条件
- 温度
- 80 °C
実験手順
107 parts by weight of 96% sulfuric acid are added dropwise within 30 minutes to 94 parts by weight of phenol at a temperature between 40° and 50° C. The mixture is then stirred for a further 2 hours at 80° C. and 182 parts by weight of isononanoic acid chloride are then added dropwise at 40° to 45° C. within 1 hour and the mixture is stirred for 1 further hour. This gives an isononanoyloxybenzenesulfonic acid having an AS content of 40% which further drops on standing at 25° C.