Calcium Carbonate → HCID 70353199、化合物

HRID 868630ノート

反応式

HRID 868630 の反応式
[C:1]([C:9]1[C:17]2[O:16][CH:15]=[CH:14][C:13]=2[CH:12]=[C:11]([CH2:18][C:19]([OH:21])=[O:20])[CH:10]=1)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[OH-].[K+].[C:24]([C:32]1[C:40]2[O:39][CH:38]=[CH:37][C:36]=2[CH:35]=[C:34]([CH2:41][C:42]([O-:44])=[O:43])[CH:33]=1)(=[O:31])[C:25]1[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=1.[K+].C(=O)([O-])[O-].[Ca+2:50].[Cl-].[NH4+].[Ca]>CO.Cl.O>[C:1]([C:9]1[C:17]2[O:16][CH:15]=[CH:14][C:13]=2[CH:12]=[C:11]([CH2:18][C:19]([O-:21])=[O:20])[CH:10]=1)(=[O:8])[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1.[Ca+2:50].[C:24]([C:32]1[C:40]2[O:39][CH:38]=[CH:37][C:36]=2[CH:35]=[C:34]([CH2:41][C:42]([O-:44])=[O:43])[CH:33]=1)(=[O:31])[C:25]1[CH:26]=[CH:27][CH:28]=[CH:29][CH:30]=1

参加物

10

反応物 6

HCID 10112Calcium Carbonate2 回HCID 14797Potassium HydroxideHCID 25517Ammonium ChlorideHCID 5460341CalciumHCID 137043977-Benzoyl-5-benzofuranacetic acidHCID 23699967HCID 23699967、化合物2 回

生成物 1

HCID 70353199HCID 70353199、化合物

試薬・触媒・溶媒 3

HCID 313Hydrochloric Acid溶媒HCID 887Methanol溶媒HCID 962Water溶媒

実験手順

To a solution of 200 mg of 7-benzoylbenzofuran-5-ylacetic acid in 5 ml of methanol is added a 1 molar equivalent of potassium hydroxide in the form of a 0.1N solution, thus, yielding a solution containing potassium 7-benzoylbenzofuran-5-ylacetate. A solution of 60 mg of calcium carbonate dissolved in the minimum amount of 1N hydrochloric acid necessary to effect solution of the calcium carbonate is buffered with 150 mg of solid ammonium chloride followed by the addition of 5 ml of water. The thus obtained buffered calcium solution is then added to the solution of potassium 7-benzoylbenzofuran-5-ylacetate and the precipitate which forms is collected by filtration, washed with water and air dried to yield calcium 7-benzoylbenzofuran-5-ylacetate.

後処理

  1. customthus, yielding a solution
  2. customThe thus obtained
  3. filtrationthe precipitate which forms is collected by filtration
  4. washwashed with water and air
  5. customdried

出典と根拠

ORDレコード
ord-dba6f3010fb043a098a32a851544e2f2
出典データセット
uspto-grants-1988_10
特許番号
US04780480

反応ノート

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