Hydrazine → 2,4-Dimethylbenzohydrazide

HRID 868751

反応式

HRID 868751 の反応式
[CH3:1][C:2]1[CH:11]=[C:10]([CH3:12])[CH:9]=[CH:8][C:3]=1[C:4](OC)=[O:5].[NH2:13][NH2:14]>CO>[CH3:1][C:2]1[CH:11]=[C:10]([CH3:12])[CH:9]=[CH:8][C:3]=1[C:4]([NH:13][NH2:14])=[O:5]

参加物

4

反応物 2

HCID 9321HydrazineHCID 32031Methyl 2,4-dimethylbenzoate

生成物 1

HCID 48461732,4-Dimethylbenzohydrazide

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

To a solution of methyl 2,4-dimethylbenzoate (2 g, 12.2 mmol) in MeOH (10 mL) was added anhydrous hydrazine (1.95 mL, 61 mmol) and the mixture was heated under reflux for 40 hours. Then the mixture was evaporated and dried under vacuum to give 2,4-dimethylbenzohydrazide as a white solid (2 g, 100%; MS (M+H, 165).

後処理

  1. temperaturethe mixture was heated
  2. temperatureunder reflux for 40 hours
  3. customThen the mixture was evaporated
  4. customdried under vacuum

出典と根拠

ORDレコード
ord-f378556826b04b0b900242b1ebc2cb1b
出典データセット
uspto-grants-2015_03
特許番号
US08968708B2

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