化工社化工社 化学情報印刷レポート · 研究参考用
Peracetic Acid → (6-Methyl-7-oxabicyclo[4.1.0]hept-3-yl)methanol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Peracetic Acid | HCID 6585 | — |
| 反応物 | 3-Cyclohexene-1-methanol, 4-methyl- | HCID 564672 | — |
| 溶媒 | Ethyl Acetate | HCID 8857 | — |
| 生成物 | (6-Methyl-7-oxabicyclo[4.1.0]hept-3-yl)methanol | HCID 86623394 | 95% |
反応手順
Epoxidation of 12.6 g (0.1 mol) of (4-methylcyclohex-3-enyl)methanol was performed with a 5 percent by weight solution of peroxyacetic acid in ethyl acetate at 65° C. The epoxidized product was purified by distillation and thereby yielded 12 g of (6-methyl-7-oxabicyclo[4.1.0]hept-3-yl)methanol with a purity of 98%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08975349B2 |
| 出典データセット | uspto-grants-2015_03 |
| ORD ID | ord-31a9f14e942a47a2a60663b414812bce |
| 出典メモ | uspto-grants-2015_03 |