Hydrochloric Acid → Ethyl(2-ethoxyethyl)phosphinic acid
反応式
[CH2:1]([P:3]([CH2:10][CH2:11][O:12][CH2:13][CH3:14])(=[O:9])[O:4]CCCC)[CH3:2].Cl>>[CH2:1]([P:3]([CH2:10][CH2:11][O:12][CH2:13][CH3:14])(=[O:4])[OH:9])[CH3:2]参加物
3
反応条件
- 温度
- 90 °C
実験手順
In a stirred apparatus, 222 g (1 mol) of butyl ethyl(2-ethoxyethyl)phosphinate (produced as in Example 7) are dissolved in 200 ml (2 mol) of concentrated hydrochloric acid. The efficiently stirred mixture is heated to about 90° C. and reacted at that temperature for about 8 hours. The water is then completely distilled off in vacuo. The residue is taken up in acetic acid and extracted. The solvent of the filtrate is removed in vacuo to obtain 156 g (94% of theory) of ethyl-(2-ethoxyethyl)phosphinic acid as oil.
後処理
- customreacted at that temperature for about 8 hours
- distillationThe water is then completely distilled off in vacuo
- extractionextracted
- customThe solvent of the filtrate is removed in vacuo
出典と根拠
- ORDレコード
- ord-b9e2c79d620845b892b03ee8162c9bde
- 出典データセット
- uspto-grants-2015_03
- 特許番号
- US08987489B2
反応ノート
読み込み中…