1-Hexene → 8Z-Tridecenyl acetate
反応式
[CH2:1]=[CH:2][CH2:3][CH2:4]CC.[C:7]([O:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH:18]=[CH2:19])(=[O:9])[CH3:8]>>[C:7]([O:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17]/[CH:18]=[CH:19]\[CH2:1][CH2:2][CH2:3][CH3:4])(=[O:9])[CH3:8]参加物
3
実験手順
Reactions between 1-hexene and 8-nonenyl acetate were conducted using methods analogous to those described above using to form the pheromone derivative 17. When catalyzed by Ruthenium complex 1, the reaction proceeded in good yield (67%) with high Z-selectivity (91%) at a low catalyst loading (0.5 mol %).
後処理
- customto form the pheromone derivative 17
- customin good yield (67%) with high Z-selectivity (91%) at a low catalyst loading (0.5 mol %)
出典と根拠
- ORDレコード
- ord-d311f3ee92db431b8a0eb371d8b2f2af
- 出典データセット
- uspto-grants-2015_03
- 特許番号
- US08987531B2
反応ノート
読み込み中…