化工社化工社 化学情報印刷レポート · 研究参考用
N-bromobutanimide → 9-Bromo-10-phenanthren-3-ylanthracene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | N-bromobutanimide | HCID 67184 | — |
| 反応物 | 9-Phenanthren-3-ylanthracene | HCID 59629500 | — |
| 溶媒 | Tetrahydrofuran | HCID 8028 | — |
| 生成物 | 9-Bromo-10-phenanthren-3-ylanthracene | HCID 59629544 | 95% |
反応手順
30 g (80 mmol) of 9-phenanthren-3-ylanthracene are suspended in 300 ml of THF, 14.2 g (80 mmol) of NBS are added, and the mixture is stirred at RT for 2 h with exclusion of light. The solvent is subsequently removed in vacuo, and the residue is boiled in EtOH and recrystallised twice from dioxane, leaving 32.9 g (95%) of bromide as yellow crystals.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08993123B2 |
| 出典データセット | uspto-grants-2015_03 |
| ORD ID | ord-ca49e2514dd84347be27c4257bab1c98 |
| 出典メモ | uspto-grants-2015_03 |