化工社化工社 化学情報印刷レポート · 研究参考用
1,7-Diphenyl-4-heptanol → HCID 178418375、化合物
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1,7-Diphenyl-4-heptanol | HCID 10539870 | — |
| 反応物 | HCID 178418459 | HCID 178418459 | — |
| 反応物 | HCID 178418471 | HCID 178418471 | — |
| 溶媒 | Tetrahydrofuran | HCID 8028 | — |
| 生成物 | HCID 178418375 | HCID 178418375 | — |
反応手順
The alcohol 137 was prepared from the crude aldehyde 136. and 1.5 mL (0.75 mmol) of 120 in 2.0 mL of THF as described above for the synthesis of alcohol 121 in Example 1 to give 220 mg of the crude diastereomeric alcohol 137. Flash chromatography (elution with 20% ethyl acetate in hexane) afforded 146 mg of the alcohol 137 as an oil. 1H NMR consistent with structure.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05723459 |
| 出典データセット | uspto-grants-1998_03 |
| ORD ID | ord-a6be5895ebf2488a874923e3878acfbe |
| 出典メモ | uspto-grants-1998_03 |