戻る
化工社化工社 化学情報印刷レポート · 研究参考用
HRID 8857作成日:2026年10月25日

Phosphoric acid, disodium salt, dodecahydrate → HCID 178418600、化合物

https://huagongshe.com/reaction/8857

反応式

関与物質

役割名称HCID仕込み量
反応物Phosphoric acid, disodium salt, dodecahydrateHCID 61456—
反応物HCID 178418801HCID 178418801—
反応物HCID 178419056HCID 178419056—
溶媒WaterHCID 962—
溶媒Sodium HydroxideHCID 14798—
生成物HCID 178418600HCID 178418600—

反応条件

温度110 °C

反応手順

2.61 Grams (10 mmol) of L-arginine methyl ester dihydrochloride, 1.11 g (3.1 mmol) of disodium phosphate 12 hydrate and 0.1 g of polyoxyethylene lauryl ether (“Newcol 1100”, nonionic surfactant produced by Nippon Nyukazai Co., Ltd.) were dissolved in 5.0 ml of water to prepare a treating agent solution. A cotton cloth (150 mm×170 mm, 4.8 g) was in advance treated to be immersed in 25% aqueous sodium hydroxide solution for an hour at room temperature, washed with water and dried. This treated cotton cloth was allowed to uniformly absorb the total amount of the above treating agent solution and then air-dried for 3 hours at room temperature. The dried cloth was heat-treated for 40 minutes at 150° C. in a batch type hot air oven (“IPHH-2000”, an inert oven manufactured by Tabaiesbeck Co., Ltd.) and washed with water. It was further washed with 5% aqueous sodium bicarbonate solution and rinsed three times with water and subsequently was washed with 10% aqueous citric acid solution and rinsed three times with water, and finally washed with household washing detergent solution, rinsed with water and air-dried. The identification of L-arginine cellulose ester was conducted by the following method. A part of the cloth was cut and a solution of ninhydrin in butanol was sprayed on it. Thereafter, it was heated for 10 minutes in an oven of 110° C. to cause coloring thereby the presence of the amino acid was confirmed. Also, a part of the cloth was cut and subjected to an infrared spectroscopic analysis whereby there was confirmed a peak based on ester bond at 1720–1740 cm−1. As a result of determination for the amount of the bonded L-arginine, it was 0.08 mmol based on 1 g of the cloth. The degree of esterfication was 0.013.

情報源と証拠

DOI10.6084/m9.figshare.5104873.v1
特許番号US07091221B2
出典データセットuspto-grants-2006_08
ORD IDord-be336cbe0bad498b911062403189f371
出典メモuspto-grants-2006_08