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Z-3-(1,3-dioxan-2-yl)-1-(2-pyridyl)-1-propene → 1-(1,3-Dioxan-2-yl)-3-(2-pyridyl)propane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Z-3-(1,3-dioxan-2-yl)-1-(2-pyridyl)-1-propene | HCID 70113689 | — |
| 触媒 | Palladium | HCID 23938 | — |
| 生成物 | 1-(1,3-Dioxan-2-yl)-3-(2-pyridyl)propane | HCID 19694139 | 92.5% |
反応手順
Through a suspension of 800 mg (4.2 mmol) of olefin 149 and 100 mg of 10% palladium on carbon was bubbled a steady stream of hydrogen gas for a period of 10 min. The reaction mixture was then filtered through celite and concentrated to give 805 mg of the acetal 150 as a colorless oil. 1H NMR consistent with structure.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05723459 |
| 出典データセット | uspto-grants-1998_03 |
| ORD ID | ord-600c0203d0174eabae949b47eb4ee810 |
| 出典メモ | uspto-grants-1998_03 |