2-Mesityl-3-nitropyridine → 2-Mesityl-3-pyridinamine

HRID 890192

反応式

HRID 890192 の反応式
[C:1]1([CH3:18])[CH:6]=[C:5]([CH3:7])[CH:4]=[C:3]([CH3:8])[C:2]=1[C:9]1[C:14]([N+:15]([O-])=O)=[CH:13][CH:12]=[CH:11][N:10]=1>[H][H].[C].[Pd]>[C:1]1([CH3:18])[CH:6]=[C:5]([CH3:7])[CH:4]=[C:3]([CH3:8])[C:2]=1[C:9]1[C:14]([NH2:15])=[CH:13][CH:12]=[CH:11][N:10]=1

参加物

4

反応物 1

HCID 222494912-Mesityl-3-nitropyridine

生成物 1

HCID 167414262-Mesityl-3-pyridinamine収率 106.5%

試薬・触媒・溶媒 2

HCID 178418390HCID 178418390、化合物触媒HCID 178418361HCID 178418361、化合物溶媒

実験手順

Palladium-carbon (10%, 0.6 g) was added to a solution of 2-mesityl-3-nitropyridine (5.99 g, 23 mmol) methanol (120 mL), followed by stirring for one day in hydrogen atmospher. The mixture was filtered through Celite and evaporated, to give the title compound (5.2 g) as white crystals.

後処理

  1. filtrationThe mixture was filtered through Celite
  2. customevaporated

出典と根拠

ORDレコード
ord-3915ad166a144395be4ef2b92973d110
出典データセット
uspto-grants-2006_02
特許番号
US06995163B2

関連ノート

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