関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Cyclohexane | HCID 8078 | — |
| 反応物 | 4-dodecyloxycarbonyl-N-hydroxyphthalimide | HCID 10915765 | — |
| 反応物 | Nitrogen Dioxide | HCID 178526396 | — |
| 触媒 | Manganous Acetate | HCID 12525 | — |
| 生成物 | Adipic Acid | HCID 196 | — |
| 生成物 | Glutaric Acid | HCID 743 | — |
| 生成物 | Cyclohexanol | HCID 7966 | — |
| 生成物 | Cyclohexanone | HCID 7967 | — |
反応手順
A mixture of 4 ml (37 mmol) of cyclohexane, 0.1 mmol of 4-dodecyloxycarbonyl-N-hydroxyphthalimide, 0.01 mmol of acetylacetonatocobalt(II), 0.001 mmol of manganese(II) acetate and 0.06 mmol of nitrogen dioxide was stirred at 80° C. in an atmosphere of air (10 atm=1 MPa) for 2 hours and thereby yielded 0.30 mmol of cyclohexyl alcohol, 0.65 mmol of cyclohexanone, 0.10 mmol of adipic acid and 0.09 mmol of glutaric acid. The total amount of the four products was 1.14 mmol, and the amount of K/A oil was 0.95 mmol.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US06998491B2 |
|---|
| 出典データセット | uspto-grants-2006_02 |
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| ORD ID | ord-088c231e604341168519ced288e0b34e |
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| 出典メモ | uspto-grants-2006_02 |
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