Cyclohexane → Adipic Acid

HRID 890843

反応式

HRID 890843 の反応式
[CH2:1]1[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.C([O:19][C:20]([C:22]1[CH:23]=[C:24]2[C:29](=[O:30])N(O)[C:26](=[O:27])[C:25]2=[CH:32][CH:33]=1)=[O:21])CCCCCCCCCCC.[N+]([O-])=[O:35]>C([O-])(=O)C.[Mn+2].C([O-])(=O)C>[CH:1]1([OH:19])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[C:22]1(=[O:35])[CH2:23][CH2:24][CH2:25][CH2:32][CH2:33]1.[C:20]([OH:19])(=[O:21])[CH2:22][CH2:23][CH2:24][CH2:25][C:26]([OH:27])=[O:35].[C:20]([OH:19])(=[O:21])[CH2:22][CH2:23][CH2:24][C:29]([OH:30])=[O:35]

参加物

8

反応物 3

HCID 8078CyclohexaneHCID 109157654-dodecyloxycarbonyl-N-hydroxyphthalimideHCID 178526396Nitrogen Dioxide

生成物 4

HCID 196Adipic AcidHCID 743Glutaric AcidHCID 7966CyclohexanolHCID 7967Cyclohexanone

試薬・触媒・溶媒 1

HCID 12525Manganous Acetate触媒

反応条件

温度
80 °C

実験手順

A mixture of 4 ml (37 mmol) of cyclohexane, 0.1 mmol of 4-dodecyloxycarbonyl-N-hydroxyphthalimide, 0.01 mmol of acetylacetonatocobalt(II), 0.001 mmol of manganese(II) acetate and 0.06 mmol of nitrogen dioxide was stirred at 80° C. in an atmosphere of air (10 atm=1 MPa) for 2 hours and thereby yielded 0.30 mmol of cyclohexyl alcohol, 0.65 mmol of cyclohexanone, 0.10 mmol of adipic acid and 0.09 mmol of glutaric acid. The total amount of the four products was 1.14 mmol, and the amount of K/A oil was 0.95 mmol.

出典と根拠

ORDレコード
ord-088c231e604341168519ced288e0b34e
出典データセット
uspto-grants-2006_02
特許番号
US06998491B2

関連ノート

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