関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Isobutylene | HCID 8255 | — |
| 反応物 | N-2-Tolylmaleimide | HCID 19989 | — |
| 反応物 | Neodecanoate | HCID 21225528 | — |
| 溶媒 | Toluene | HCID 1140 | — |
| 生成物 | N-(2-methylphenyl)maleimide isobutene | HCID 69442194 | — |
反応手順
In a one-liter autoclave were charged 400 ml of toluene as a polymerization solvent, 0.001 moles of perbutyl neodecanoate as a polymerization initiator, 0.42 moles of N-(2-methylphenyl)maleimide, and 4.05 moles of isobutene, and the mixture was subjected to polymerization reaction under a polymerization condition at a polymerization temperature of 60° C. for a polymerization time of 5 hours, to obtain N-(2-methylphenyl)maleimide-isobutene alternating copolymer. The thus obtained N-(2-methylphenyl)maleimide-isobutene alternating copolymer had a weight average molecular weight (Mw) (as reduced into standard polystyrene) of 160,000 and a molecular weight distribution (Mw/Mn), which is expressed by [(weight average molecular weight (Mw))/(number average molecular weight (Mn))], of 2.7.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 特許番号 | US07001967B2 |
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| 出典データセット | uspto-grants-2006_02 |
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| ORD ID | ord-20cd0d7e689248e394b863043ba2525e |
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| 出典メモ | uspto-grants-2006_02 |
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