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Isobutylene → N-(2,6-diethylphenyl)maleimide isobutene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Isobutylene | HCID 8255 | — |
| 反応物 | 1-(2,6-diethylphenyl)-1H-pyrrole-2,5-dione | HCID 300890 | — |
| 反応物 | Neodecanoate | HCID 21225528 | — |
| 溶媒 | Toluene | HCID 1140 | — |
| 生成物 | N-(2,6-diethylphenyl)maleimide isobutene | HCID 68407703 | — |
反応手順
In a one-liter autoclave were charged 400 ml of toluene as a polymerization solvent, 0.001 moles of perbutyl neodecanoate as a polymerization initiator, 0.42 moles of N-(2,6-diethylphenyl)maleimide, and 4.05 moles of isobutene, and the mixture was subjected to polymerization reaction under a polymerization condition at a polymerization temperature of 60° C. for a polymerization time of 5 hours, to obtain N-(2,6-diethylphenyl)maleimide-isobutene alternating copolymer. The thus obtained N-(2,6-diethylphenyl)maleimide-isobutene alternating copolymer had a weight average molecular weight (Mw) (as reduced into standard polystyrene) of 170,000 and an Mw/Mn of 2.6.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07001967B2 |
| 出典データセット | uspto-grants-2006_02 |
| ORD ID | ord-83c839dd95dc4cd6a3de8857d7f8c45d |
| 出典メモ | uspto-grants-2006_02 |