Diethylamine → 3-Hydroxy-2-cyclobuten-1-one-diethylammonium salt

HRID 892647

反応式

HRID 892647 の反応式
[C:1]1(=[O:6])[CH2:4][C:3](=[O:5])[CH2:2]1.[CH2:7]([NH:9][CH2:10][CH3:11])[CH3:8]>C(OCC)(=O)C>[CH2:7]([NH2+:9][CH2:10][CH3:11])[CH3:8].[OH:6][C:1]1[CH2:4][C:3](=[O:5])[CH:2]=1

参加物

4

反応物 2

HCID 8021DiethylamineHCID 27357Cyclobutane-1,3-dione

生成物 1

HCID 198960273-Hydroxy-2-cyclobuten-1-one-diethylammonium salt収率 83.8%

試薬・触媒・溶媒 1

HCID 8857Ethyl Acetate溶媒2 回

実験手順

2.1 g of 1,3-cyclobutanedione (23.0 mmol) was suspended in 40 g of ethyl acetate. A solution of 1.84 g of diethylamine (25.0 mmol) in 10 g of ethyl acetate was instilled in this suspension at 20° C. within 15 minutes. After 1 hour of stirring at room temperature, the suspension was filtered and then dried. 3.05 g of the title product with a purity (according to HPLC) of 93.7 percent, corresponding to a yield of 79.2 percent, relative to the cyclobutanedione, was obtained. Data for the title compound was:

後処理

  1. filtrationthe suspension was filtered
  2. customdried

出典と根拠

ORDレコード
ord-d55b0dc87a7e4ec2915e7323c526cebc
出典データセット
uspto-grants-1992_06
特許番号
US05118847

関連ノート

読み込み中…