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Styrene → 1-Octene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Styrene | HCID 7501 | — |
| 反応物 | Trifluoromethanesulfonyl chloride | HCID 79000 | — |
| 反応物 | 1,1,2,2,3,3,4,4,5,5,6,6,6-Tridecafluorohexane-1-sulphonyl chloride | HCID 100374 | — |
| 生成物 | 1-Octene | HCID 8125 | — |
| 生成物 | 1-Hexene | HCID 11597 | — |
| 生成物 | 1-Heptene | HCID 11610 | — |
反応手順
Reactions were carried out generally in accordance with Example 1, except that trifluoromethanesulfonyl chloride was replaced by perfluorohexanesulfonyl chloride and styrene was replaced, respcetively, by 1-hexene (Example 15), 1-heptene (Example 16) and 1-octene (Example 17), whereby 1-butyl-1-chloro-2-perfluorohexylethane (Example 15), 1-heptyl-1-chloro-2-perfluorohexylethane (Example 16) and 1-hexyl-1-chloro-2-perfluorohexylethane (Example 17) were obtained, respectively, at a yield of 63%, 69% and 73%. The results of analyses of respective products are set forth below.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05118879 |
| 出典データセット | uspto-grants-1992_06 |
| ORD ID | ord-1f97f4870f714f069b7a4546ba978e7f |
| 出典メモ | uspto-grants-1992_06 |