p-Anisoyl chloride → HCID 69959091、化合物

HRID 893850

反応式

HRID 893850 の反応式
[CH2:1]([O:3][C:4]([CH:6]1[CH:14]2[C:9]3([CH:18]=[CH:17][CH:16]=[CH:15][C:10]3=[N:11][CH2:12][CH2:13]2)[S:8][CH2:7]1)=[O:5])[CH3:2].[C:19](OC(=O)C)(=[O:21])[CH3:20].[CH3:26][O:27][C:28]1[CH:36]=[CH:35][C:31]([C:32](Cl)=[O:33])=[CH:30][CH:29]=1.ClC1C=CC=CC=1C(Cl)=O>>[CH2:1]([O:3][C:4]([CH:6]1[CH:14]2[C:9]3([CH:18]=[CH:17][CH:16]=[CH:15][C:10]3=[N:11][CH2:12][CH2:13]2)[S:8][CH:7]1[C:19](=[O:21])[CH3:20])=[O:5])[CH3:2].[CH2:1]([O:3][C:4]([CH:6]1[CH:14]2[C:9]3([CH:18]=[CH:17][CH:16]=[CH:15][C:10]3=[N:11][CH2:12][CH2:13]2)[S:8][CH:7]1[C:32](=[O:33])[C:31]1[CH:35]=[CH:36][C:28]([O:27][CH3:26])=[CH:29][CH:30]=1)=[O:5])[CH3:2]

参加物

6

反応物 4

HCID 7477p-Anisoyl chlorideHCID 7918Acetic AnhydrideHCID 691102-Chlorobenzoyl chlorideHCID 199609281,2,3,4-Tetrahydro-benzo[b]thieno[2,3,c]pyridine-3-carboxylic acid ethyl ester

生成物 2

HCID 69959091HCID 69959091、化合物HCID 69959664HCID 69959664、化合物

実験手順

2-Acetyl-1,2,3,4-tetrahydro-benzo[b]thieno[2,3-c]pyridine-3-carboxylic acid ethyl ester and 2-(4-methoxybenzoyl)-1,2,3,4-tetrahydro-benzo[b]thieno[2,3-c]pyridine-3-carboxylic acid ethyl ester were synthesized using 1,2,3,4-tetrahydro-benzo[b]thieno[2,3-c]pyridine-3-carboxylic acid ethyl ester as the starting material by following the same procedure as in Example 5 except that 324 mg of acetic anhydride or 510 mg of 4-methoxybenzoyl chloride, respectively, in place of 614 mg of 2-chlorobenzoyl chloride in Example 5.

出典と根拠

ORDレコード
ord-c82d6f31bd804c8dac44808a15e1856d
出典データセット
uspto-grants-1992_06
特許番号
US05126448

関連ノート

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