Acetic Anhydride → 5-acetylaminospiro[benzo[b]furan-2(3H),1'-cyclopropane]-3-one
反応式
[NH2:1][C:2]1[CH:13]=[CH:12][C:5]2[O:6][C:7]3([C:10](=[O:11])[C:4]=2[CH:3]=1)[CH2:9][CH2:8]3.[C:14](OC(=O)C)(=[O:16])[CH3:15]>C(O)(=O)C>[C:14]([NH:1][C:2]1[CH:13]=[CH:12][C:5]2[O:6][C:7]3([C:10](=[O:11])[C:4]=2[CH:3]=1)[CH2:9][CH2:8]3)(=[O:16])[CH3:15]参加物
4
実験手順
5-Aminospiro[benzo[b]furan-2(3H),1'-cyclopropane]-3-one (0.875 g.) was acetylated with acetic anhydride (7 ml.) and acetic acid (7 ml.) and the acetylation product was recrystallized from ethanol. By the above procedure there was obtained 5-acetylaminospiro[benzo[b]furan-2(3H),1'-cyclopropane]-3-one as yellow prisms melting at 211°-212° C.
後処理
- customthe acetylation product was recrystallized from ethanol
出典と根拠
- ORDレコード
- ord-05dd96b16943472b8db851c04fa5c8e2
- 出典データセット
- uspto-grants-1981_08
- 特許番号
- US04284644
反応ノート
読み込み中…