tert-Butyl (3-aminopropyl)carbamate → HCID 22350985、化合物

HRID 896628ノート

反応式

HRID 896628 の反応式
[N:1]1[CH:6]=[CH:5][CH:4]=[CH:3][C:2]=1[NH:7][C:8](=[S:12])SCC.[NH2:13][CH2:14][CH2:15][CH2:16][NH:17][C:18](=[O:24])[O:19][C:20]([CH3:23])([CH3:22])[CH3:21]>>[N:1]1[CH:6]=[CH:5][CH:4]=[CH:3][C:2]=1[NH:7][C:8]([NH:13][CH2:14][CH2:15][CH2:16][NH:17][C:18](=[O:24])[O:19][C:20]([CH3:22])([CH3:21])[CH3:23])=[S:12]

参加物

3

反応物 2

HCID 2735700tert-Butyl (3-aminopropyl)carbamateHCID 12214896Ethyl 2-Pyridyldithiocarbamate

生成物 1

HCID 22350985HCID 22350985、化合物収率 89.7%

実験手順

In a similar manner to in Reference Example 58, ethyl 2-pyridyldithiocarbamate (1.98 g) and t-butyl 3-aminopropylcarbamate (1.74 g) were reacted and crystallized from n-hexane-diethyl ether to give the title compound (2.78 g).

後処理

  1. customcrystallized from n-hexane-diethyl ether

出典と根拠

ORDレコード
ord-959864f4240340ab9e820278039b08ab
出典データセット
uspto-grants-2005_07
特許番号
US06919361B2

反応ノート

読み込み中…