alpha-Methyl-2-furanethanol → Furfuryl methyl ketone

HRID 900438ノート

反応式

HRID 900438 の反応式
[O:1]1[CH:5]=[CH:4][CH:3]=[C:2]1[CH2:6][CH:7]([OH:9])[CH3:8].[Cr](Cl)([O-])(=O)=O.[NH+]1C=CC=CC=1>ClCCl>[O:1]1[CH:5]=[CH:4][CH:3]=[C:2]1[CH2:6][C:7](=[O:9])[CH3:8]

参加物

4

反応物 2

HCID 10855456alpha-Methyl-2-furanethanolHCID 178418287HCID 178418287、化合物

生成物 1

HCID 228583Furfuryl methyl ketone

試薬・触媒・溶媒 1

HCID 6344Dichloromethane溶媒

実験手順

To a solution of 1-(2-furyl)-propan-2-ol (3.25 g) in dichloromethane (200 ml) was added in one portion pyridinium chlorochromate (13.0 g). The resulting mixture was stirred at room temperature for 5 h and then filtered through a small bed of silica. The organics were evaporated to give the crude product which was used without further purification (3.53 g).

後処理

  1. filtrationfiltered through a small bed of silica
  2. customThe organics were evaporated

出典と根拠

ORDレコード
ord-4683adfa5749461e8b7a09aaf60e18b8
出典データセット
uspto-grants-2008_04
特許番号
US07358376B2

反応ノート

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